Near-infrared laboratory spectra of solid H₂O/CO₂ and CH₃OH/CO₂ ice mixtures     

Max P. Bernstein  Dale P. Cruikshank  Scott A. Sandford 《Icarus》2005,179(2):527-534

We present near-IR spectra of solid CO₂ in H₂O and CH₃OH, and find they are significantly different from that of pure solid CO₂. Peaks not present in either pure H₂O or pure CO₂ spectra become evident when the two are mixed. First, the putative theoretically forbidden CO₂ (2ν₃) overtone near 2.134 μm (4685 cm⁻¹), that is absent from our spectrum of pure solid CO₂, is prominent in the spectra of H₂O/CO₂=5 and 25 mixtures. Second, a 2.74-μm (3650 cm⁻¹) dangling OH feature of H₂O (and a potentially related peak at 1.89 μm) appear in the spectra of CO₂-H₂O ice mixtures, but are probably not diagnostic of the presence of CO₂. Other CO₂ peaks display shifts in position and increased width because of intermolecular interactions with H₂O. Warming causes some peak positions and profiles in the spectrum of a H₂O/CO₂=5 mixture to take on the appearance of pure CO₂. Absolute strengths for absorptions of CO₂ in solid H₂O are estimated. Similar results are observed for CO₂ in solid CH₃OH. Since the CO₂ (2ν₃) overtone near 2.134 μm (4685 cm⁻¹) is not present in pure CO₂ but prominent in mixtures, it may be a good observational (spectral) indicator of whether solid CO₂ is a pure material or intimately mixed with other molecules. These observations may be applicable to Mars polar caps as well as outer Solar System bodies.  相似文献   

A Very Small Array search for the extended Sunyaev–Zel''dovich effect in the Corona Borealis supercluster     

Ricardo Génova-Santos  José Alberto Rubiño-Martín  Rafael Rebolo †  Kieran Cleary ‡  Rod D. Davies  Richard J. Davis  Clive Dickinson §  Nelson Falcón ‡‡  Keith Grainge  Carlos M. Gutiérrez  Michael P. Hobson  Michael E. Jones ¶  Rüdiger Kneissl &#;  Katy Lancaster  Carmen P. Padilla-Torres  Richard D. E. Saunders  Paul F. Scott  Angela C. Taylor ¶  Robert A. Watson †† 《Monthly notices of the Royal Astronomical Society》2005,363(1):79-92

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Assessment of the interstellar processes leading to deuterium enrichment in meteoritic organics     

Scott A. SANDFORD  Max P. BERNSTEIN  Jason P. DWORKIN 《Meteoritics & planetary science》2001,36(8):1117-1133

Abstract— The presence of isotopic anomalies is the most unequivocal demonstration that meteoritic material contains circumstellar or interstellar components. In the case of organic compounds in meteorites and interplanetary dust particles (IDPs), the most useful isotopic tracer has been deuterium (D). We discuss four processes that are expected to lead to D enrichment in interstellar materials and describe how their unique characteristics can be used to assess their relative importance for the organics in meteorites. These enrichment processes are low‐temperature gas phase ion‐molecule reactions, low‐temperature gas‐grain reactions, gas phase unimolecular photodissociation, and ultraviolet photolysis in D‐enriched ice mantles. Each of these processes is expected to be associated with distinct regiochemical signatures (D placement on the product molecules, correlation with specific chemical functionalities, etc.), especially in the molecular population of polycyclic aromatic hydrocarbons (PAHs). We describe these differences and discuss how they may be used to delineate the various interstellar processes that may have contributed to meteoritic D enrichments. We also briefly discuss how these processes may affect the isotopic distributions in C, O, and N in the same compounds.  相似文献   

    

Scott Painter 《Mathematical Geology》1995,27(7):813-830

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X-Ray Line Transfer in Plasmas with Large Velocity Gradients     

F. M. Kerr  A. Gouveia  R. W. Lee  P. K. Patel  O. Renner  S. J. Rose  H. A. Scott  J. S. Wark 《Astrophysics and Space Science》2005,298(1-2):171-176

An astrophysically relevant experiment is compared to the output of a multidimensional radiation transfer code in which populations and radiation are self-consistently treated. Experimental Al Ly α spectra obtained with a very high-resolution spectrometer are presented as quantitative evidence of dot plasma non-planar expansion. Analysis of these spectra using the code is performed, in particular examining the effects of velocity gradients in directions other than that of the primary expansion. These calculations are found to be in good agreement with the experimental results. Usage of the Ly α doublet as a planarity diagnostic is discussed.  相似文献   

NIGHTGLOW: an instrument to measure the Earth’s nighttime ultraviolet glow—results from the first engineering flight     

Louis M. Barbier  Robert Smith  Scott Murphy  Eric R. Christian  Rodger Farley  John F. Krizmanic  John W. Mitchell  Robert E. Streitmatter  Eugene C. Loh  Stephen Stochaj 《Astroparticle Physics》2005,22(5-6):439-449

We have designed and built an instrument to measure and monitor the “nightglow” of the Earth’s atmosphere in the near ultraviolet (NUV). In this paper we describe the design of this instrument, called NIGHTGLOW. NIGHTGLOW is designed to be flown from a high altitude research balloon, and circumnavigate the globe. NIGHTGLOW is a NASA, University of Utah, and New Mexico State University project. A test flight took place from Palestine, Texas on July 5, 2000, lasting about 8 h. The instrument performed well and landed safely in Stiles, Texas with little damage. The resulting measurements of the NUV nightglow are compared with previous measurements from sounding rockets and balloons.  相似文献   

Concentrating Antarctic meteorites on blue ice fields—The Frontier Mountain meteorite trap     

Scott A. Sandford 《Meteoritics & planetary science》2002,37(2):151-151

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Fossil hyrax dung and evidence of Late Pleistocene and Holocene vegetation types in the Namib Desert     

Louis Scott  Eugene Marais  George A. Brook 《第四纪科学杂志》2004,19(8):829-832

Pollen was derived from fossil dung of herbivorous hyraxes, deposited in a rock shelter on the highest mountain in Namibia, Dâures or Brandberg, situated on the Namib Desert margin. Radiocarbon dating ranging in age between modern times and 30 000 yr BP showed it represents the first empirical pollen evidence of continental palaeovegetation during the Late Pleistocene along the western escarpment of southern Africa. The initial results indicate Last Glacial Maximum vegetation differed totally from the current pattern as vegetation types were dominated by small Asteraceae shrubs, in contrast to those of the Holocene and modern times which show more succulents, grass and woody elements (arboreal pollen). The results suggest that Cape floral communities did not reach into the tropics along the western escarpment of Africa, despite such pollen types occurring in marine cores. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

A revised model for cycloid growth mechanics on Europa: Evidence from surface morphologies and geometries     

Scott T. Marshall 《Icarus》2005,177(2):341-366

Although a single model currently exists to explain the development of curved Europan cycloids, there have been no systematic studies of the range of morphologies and quantifiable geometric parameters of cycloidal features. We address variations in geometry along individual cycloid segments, characterizing differences in cusp styles and angles, and addressing the morphologic aspects of cycloid segments and cusps. In so doing, we illustrate how geometric and morphologic evidence imply a formation mechanism that differs from the existing model in several aspects. The current model states that cycloids are initiated as tensile fractures that grow in a curved path in response to rotating diurnal tidal stresses on Europa. However, the geometry of a cycloid cusp necessitates that shear stress was resolved onto the existing cycloid segment by the rotating diurnal stresses at the instant of cusp formation. Furthermore, we observe that cycloid cusps have a strikingly similar geometry to tailcracks that developed at the tips of many ridge-like strike-slip faults on Europa in response to shearing at the fault tip. We suggest that this similarity in geometries can be attributed to an identical formation mechanism whereby cycloid cusps form by a tailcracking process. We therefore present a revised, mechanically-based model for cycloid formation that retains the basic premise that crack growth is governed by diurnal stresses, but describes the development of cycloid cusps in response to resolved shear stresses at the tips of existing cycloid segments. The ratio of normal to shear stress at the time of tailcrack formation dictates the cusp angle and, over longer time periods, influences the morphologic evolution of the cycloid segment as it is repeatedly reworked by tidal stresses.  相似文献   

The baseline intracluster entropy profile from gravitational structure formation     

G. Mark Voit  Scott T. Kay  Greg L. Bryan 《Monthly notices of the Royal Astronomical Society》2005,364(3):909-916

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